Where it can start to get slightly tricky is in dealing with line diagrams containing implicit (“hidden”) hydrogens and lone pairs.Ĭhemists like time-saving shortcuts just as much as anybody else, and learning to quickly interpret line diagrams is as fundamental to organic chemistry as learning the alphabet is to written English. Sp hybridization: sum of attached atoms + lone pairs = 2 Sp 2 hybridization: sum of attached atoms + lone pairs = 3 Sp 3 hybridization: sum of attached atoms + lone pairs = 4 Some Simple Worked Examples Of The Hybridization Shortcut “Geometry Determines Hybridization, Not The Other Way Around”ġ.Lone Pairs In P-Orbitals (Versus Hybrid Orbitals) Have Better Orbital Overlap With Adjacent Pi Systems.Exception #1: Lone Pairs Adjacent To Pi-bonds.How To Determine Hybridization Of An Atom: Two Exercises.Some Simple Worked Examples Of The Hybridization Shortcut. ![]() The main exception is atoms with lone pairs that are adjacent to pi bonds, which we’ll discuss in detail below. ![]()
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